Let us use the first 3 digits of PI, i.e. 3,1,4 to create numbers from 1 to 50, using only basic math. operators.
Not all the digits must be used, but none can be repeated.

Examples (out of this range): 52= 13*4; 65=4^3+1; 84=14*3!

Only few numbers cannot be achieved.

Please show your list.